Mechanism of Allyl Alcohol Epoxidation with Hydrogen Peroxide at Titanium Catalyst (Ts-1)

Authors

  • Z Y Pastukhova
  • L G Bruk
  • V R Flid

DOI:

https://doi.org/10.18502/keg.v3i4.2230

Abstract

Allyl alcohol epoxidation mechanism at the titanosilicate was studied. The best results were obtained for the hypothesis involving the hydrogen peroxide and allyl alcohol adsorption at the active catalyst centres with subsequent interaction of the surface intermediates with each other, with the formation of glycidol adsorbed on the active centre, free catalyst centre and molecule of water

References

Beck C, Mallat T and Baiker A 2003 Catalysis Letters 88 203-09.

Pastukhova Zh Yu, Nasybulin F D, Sulimov A V, Flid V R and Bruk L GEpoxidation of allyl alcohol to glycidol with hydrogen peroxide at titanium silicalite 2016 Fine Chemical Technologies 11 26-34.

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Published

2018-05-07

How to Cite

Pastukhova, Z. Y., Bruk, L. G., & Flid, V. R. (2018). Mechanism of Allyl Alcohol Epoxidation with Hydrogen Peroxide at Titanium Catalyst (Ts-1). KnE Engineering, 3(5), 93–96. https://doi.org/10.18502/keg.v3i4.2230

Issue

Russian Forum of Young Scientists (RFYS)

Section

Articles