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Pastukhova, Z. Y., Bruk, L. G., & Flid, V. R. (2018). Mechanism of Allyl Alcohol Epoxidation with Hydrogen Peroxide at Titanium Catalyst (Ts-1). KnE Engineering, 3(5), 93–96. https://doi.org/10.18502/keg.v3i4.2230

https://doi.org/10.18502/keg.v3i4.2230

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authors

  • Z Y Pastukhova
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  • L G Bruk
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  • V R Flid
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Published Date

  • May 7, 2018

Mechanism of Allyl Alcohol Epoxidation with Hydrogen Peroxide at Titanium Catalyst (Ts-1)

KnE Engineering / Russian Forum of Young Scientists (RFYS) / Pages 93–96

Abstract

Allyl alcohol epoxidation mechanism at the titanosilicate was studied. The best results were obtained for the hypothesis involving the hydrogen peroxide and allyl alcohol adsorption at the active catalyst centres with subsequent interaction of the surface intermediates with each other, with the formation of glycidol adsorbed on the active centre, free catalyst centre and molecule of water

References
[1] Beck C, Mallat T and Baiker A 2003 Catalysis Letters 88 203-09.


[2] Pastukhova Zh Yu, Nasybulin F D, Sulimov A V, Flid V R and Bruk L GEpoxidation of allyl alcohol to glycidol with hydrogen peroxide at titanium silicalite 2016 Fine Chemical Technologies 11 26-34.