Synthesis and Attestation of Titanium Dioxide Nanotubes Based Photocatalyst for Water and Air Purification out of Harmful Organic Impurities

Abstract

In the present work we have synthesized nanotubular TiO2 film with a nonstoichiometric layer in the vicinity of titanium foil by anodization during 120 min. The catalytic activity of nanotubular titanium dioxide films formed during the oxidation of acetone to carbon dioxide under the action of visible light with a wavelength of 450 nm was found to be approximately 2 times higher compared to standard titanium dioxide (Degussa P25). Such a pronounced enhancement of activity may be attributed to a more efficient absorption of visible light by the films due to narrowing of the optical gap because of difference in the nonstoichiometry of titanium dioxide near the interface between nanotubular film and the titanium foil substrate.


Keywords: photocatalysis, nonstoichiometric titanium dioxide, purification of water

References
[1] Higashimoto, S., et al. (2010). Efficient and Selective Oxidation of Benzylic Alcohol by O2 into Corresponding Aldehydes on a Tio2 Photocatalyst under Visible Light Irradiation: Effect of Phenyl-Ring Substitution on the Photocatalytic Activity. Journal of Catalysis, vol. 276, pp. 76-83.

[2] Popkov VI, Bachina AK, Valeeva AA, Lobinsky AA, Gerasimov EY, Rempel AA. (2020) Synthesis, morphology and electrochemical properties of spherulite titania nanocrystals. Ceramics International, vol. 46, pp. 24483-24487.

[3] Rempel AA, Valeeva AA. (2019) Nanostructural titanium dioxide for medical chemistry. Russian chemical bulletin, Int. Ed. vol.68, pp. 2163-2171.

[4] Chen, X. and Mao, S. S. (2007). Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications. Chem. Rev., vol. 107, pp. 2891-2959.

[5] Vasilevskaia AK, Popkov VI, Valeeva AA, Rempel AA. (2016). Formation of nonstoichiometric titanium oxides nanoparticles Tin O2n–1 upon heat-treatments of titanium hydroxide and anatase nanoparticles in a hydrogen flow. Russ. J. Appl. Chem., vol. 89, pp.1211–1220. .

[6] Dorosheva I.B, Valeeva A.A, Rempel A.A. (2017). Sol-gel synthesis of nanosized titanium dioxide at various pH of the initial solution. AIP Conf. Proc., vol.1886, p.020006.

[7] Li, C-J., et al. (2012). High Selectivity in Visible-Light-Driven Partial Photocatalytic Oxidation of Benzyl Alcohol into Benzaldehyde over Single-Crystalline Rutile Tio2 Nanorods. Applied Catalysis B: Environmental, vols. 115-116, pp. 201-208.

[8] Rempel A.A, Kozlova E.A, Gorbunova T.I, Cherepanova S.V, Gerasimov E.Y, Kozhevnikova N.S, Valeeva A.A, Korovin E.Y, Kaichev V.V, Shchipunov Y.A. (2015) Synthesis and solar light catalytic properties of titania-cadmium sulfide hybrid nanostructures. Catalysis Communications, vol. 68, pp. 61-66.

[9] Rempel A.A, Kuznetsova Y.V, Dorosheva I.B, Valeeva A.A, Weinstein I.A, Kozlova E.A, Saraev A.A, Selishchev D.S. (2020). High photocatalytic activity under visible light of sandwich structures based on anodic TiO2/CdS nanoparticles/sol-gel /CdS nanoparticles/sol-gel. Topics in Catalysis, vol. 63, pp. 130-138.

[10] Carp, O., Huisman, C. L. and Reller A. (2004). Photoinduced Reactivity of Titanium Dioxide. Progress in Solid State Chemistry, vol. 32, pp. 33-177.

[11] Valeeva, A. A., et al. (2018). Nonstoichiometric Titanium Dioxide Nanotubes with Enhanced Catalytical Activity under Visible Light. Scientific Reports – Nature, vol. 8, pp. 9607-9617.

[12] Vokhmintsev, A. S., et al. (2014). Memristive Effect in a Nanotubular Layer of Anodized Titanium Dioxide. Bulletin of the Russian Academy of Sciences: Physics, issue 78, pp. 1176-1179.

[13] Alivov, Y. and Fan Z. (2009). A TiO2 Nanostructure Transformation: From Ordered Nanotubes to Nanoparticles. Nanotechnology, vol. 20, pp.1-6.

[14] Valeeva, A. A., et al. (2019). Influence of Calcination on Photocatalytic Properties of Nonstoichiometric Titanium Dioxide Nanotubes. Alloys and Compounds, vol. 796, pp. 293-299.