Green Chemistry on the Ores Leaching Processes Using Organic Acids: A Qualitative Pedagogical Content Analysis Study

Abstract

Ores leaching projects aimed to recover toxic and valuable metals from industrial residues. Organic acids like acetic acid and methanesulfonic acid were chosen as leaching agents because they have high selectivity on low concentrations of metals and low toxicity. This study aimed to obtain scientists’ conceptions of ores leaching using organic acids presented in concept maps and Teaching Learning Sequence (TLS). The method used in this study was qualitative content analysis consisting of literature collection, descriptive analysis, category selection, and material evaluation from textbooks, review articles and research articles. The result of this study was in the form of a concept map, and TLS illustrate five sequences of learning materials consisting of mineral products in Indonesia, valorization of industrial process residue with green chemistry-oriented, industrial process residue treatment steps, organic acid properties, and examples of the ores leaching process. The leaching process of ores using organic acids in learning is contextual learning that integrates the concepts of acids and bases, redox reactions, and the principles of solubility learned by high school students. This process also applies the principles of green chemistry, preventing waste in the process and using safe solvents. The results of the concept map and Teaching Learning Sequence (TLS) showed the application of green chemistry in learning, which is expected to be used as a design for teaching materials and didactic designs that can support education for sustainable development.


Keywords: Green Chemistry, Organic Acids, Pedagogical Content Analysis

References
[1] BPS. Produksi barang tambang mineral. Jakarta; 2021.

[2] OECD. Global material resources outlook to 2060. Paris, France: OECD; 2019.

[3] Dalvi AD, Bacon WG, Osborne RC. The past and the future of Nickel laterites world’s land based Nickel resources and primary Nickel production Nickel production. International Convention, Trade Show & Investors Exchange; 2004.1–27

[4] Besser AD, Sorokina VS, Sokolov OK, Paretskii VM. Processing of utilized lead-acid storage batteries—the basis of lead recycling. Russ Metall. 2009;2009(8):781–7.

[5] Wang Z, Li Y, Zhang G. Fabrication of Superhydrophobic Zn-Ni Coatings on LA43M Magnesium Alloy. Journal of Materials Engineering and Performance. 2022. https://doi.org/10.1007/s11665-022-06670-2.

[6] Dutrizac JE, Jambor JL. Jarosites and their application in hydrometallurgy. Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance. 2019;40:405–52.

[7] Palden T. Organic lixiviants for metal recovery from industrial process residues. Faculty Of Science, Department Of Chemistry Molecular Design & Synthesis. 2021.

[8] Palden T, MacHiels L, Regadió M, Binnemans K. Antimony recovery from lead-rich dross of lead smelter and conversion into Antimony Oxide Chloride (Sb4O5Cl2). ACS Sustain Chem& Eng. 2021;9(14):5074–84.

[9] Anastas PT, Irvin J. Levy Green chemistry education: changing the course of chemistry. American Chemical Society; 1st edition 2009.

[10] Gernon MD, Wu M, Buszta T, Janney P. Environmental benefits of methanesulfonic acid: comparative properties and advantages. Green Chem. 1999;1(3):127–40.

[11] Mayring P. Qualitative content analysis: Theoretical foundation, basic procedures and software solution. Forum Qualitative Sozialforschung/Forum: Qualitative Social Research. 2014;October

[12] Thomas DR. A general inductive approach for analyzing qualitative evaluation data. Am J Eval. 2006;27(2):237–46.

[13] Binnemans K, Jones PT. Solvometallurgy: an emerging branch of extractive metallurgy. J Sustain Metall. 2017;3(3):570–600.

[14] Asokan P, Saxena M, Asolekar SR. Recycling hazardous jarosite waste using coal combustion residues. Mater Charact. 2010;61(12):1342–55.

[15] Haldar SK. Mineral processing. Mineral Exploration. Elsevier; 2018. pp. 259–90.

[16] Brady A. J. E., N.D. Jespersen, and Hyslop, Chemistry the molecular nature of matter. John Wiley and Sons, Inc. United State; 2021.

[17] Papagianni M. Organic acids. Comprehensive Biotechnology. Elsevier; 2011. pp. 109– 20.

[18] Speight JG. Chemical and physical properties. Reaction Mechanisms in Environmental Engineering. Elsevier; 2018. pp. 81–114.