Red Mud as an Additional Source of Titanium Raw Materials

Abstract

In this study the extraction of titanium from bauxite residue (red mud) with 2 step acid leaching was proposed. In the first step red mud was leached with diluted hydrochloric acid under stirring to remove the soluble Ca, Na, Al, Si and K at 25 0C and pH=3 for 1 hour. The content of iron and titanium in the solid residue increased to 57.7% and 6.4%, respectively. The factors influencing sulfuric acid leaching of the solid residue in the second stage were examined by factorial design. The optimal iron and titanium extraction efficiency was obtained after leaching at 50 oC and L:S ration 20:1 for 90 min when 80 g/L sulfuric acid was used. The titanium oxide content in the concentrate obtained under the optimum conditions amounted to 46.7%. The maximum recovery of titanium in the sulfuric acid solution has not exceeded 6%.


Keywords: red mud, acid leaching, TiO2, iron extraction, precipitation, comprehensive utilization

References
[1] Y. Liu and R. Naidu, “Hidden values in bauxite residue (red mud): Recovery of metals,” Waste Management, vol. 34, no. 12, pp. 2662–2673, 2014.


[2] I. V. Loginova, A. A. Shoppert, and L. I. Chaikin, “Extraction of Rare-Earth Metals During the Systematic Processing of Diaspore-Boehmite Bauxites,” Metallurgist, pp. 1–6, 2016.


[3] D.-Q. Zhu, T.-J. Chun, J. Pan, and Z. He, “Recovery of Iron From High-Iron Red Mud by Reduction Roasting With Adding Sodium Salt,” Journal of Iron and Steel Research International, vol. 19, no. 8, pp. 1–5, 2012.


[4] Y.-H. Guo, J.-J. Gao, H.-J. Xu, K. Zhao, and X.-F. Shi, “Nuggets Production by Direct Reduction of High Iron Red Mud,” Journal of Iron and Steel Research International, vol. 20, no. 5, pp. 24–27, 2013.


[5] W. Liu, S. Sun, L. Zhang, S. Jahanshahi, and J. Yang, “Experimental and simulative study on phase transformation in Bayer red mud soda-lime roasting system and recovery of Al, Na and Fe,” Minerals Engineering, vol. 39, pp. 213–218, 2012.


[6] R. A. Pepper, S. J. Couperthwaite, and G. J. Millar, “Comprehensive examination of acid leaching behaviour of mineral phases from red mud: Recovery of Fe, Al, Ti, and Si,” Minerals Engineering, vol. 99, pp. 8–18, 2016.


[7] Y. Yang, X. Wang, M. Wang, H. Wang, and P. Xian, “Recovery of iron from red mud by selective leach with oxalic acid,” Hydrometallurgy, vol. 157, pp. 239–245, 2015.


[8] G. Li, M. Liu, M. Rao, T. Jiang, J. Zhuang, and Y. Zhang, “Stepwise extraction of valuable components from red mud based on reductive roasting with sodium salts,” Journal of Hazardous Materials, vol. 280, pp. 774–780, 2014.


[9] Y. Huang, W. Chai, G. Han, W. Wang, S. Yang, and J. Liu, “A perspective of stepwise
utilisation of Bayer red mud: Step two-Extracting and recovering Ti from Ti-enriched tailing with acid leaching and precipitate flotation,” Journal of Hazardous Materials, vol. 307, pp. 318–327, 2016.


[10] Y. Song, M. Wang, J. Liang, and L. Zhou, “High-rate precipitation of iron as jarosite by using a combination process of electrolytic reduction and biological oxidation,” Hydrometallurgy, vol. 143, pp. 23–27, 2014.


[11] J. E. Dutrizac, “Comparative rates of precipitation of ammonium jarosite and sodium jarosite in ferric sulphate - sulphuric acid media,” Canadian Metallurgical Quarterly, vol. 49, no. 2, pp. 121–130, 2010.