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Vasilievich, B. I., Isaevich, G. I., Yuryevich, T. E., Yuryevich, T. D., & Nikolaevich, R. E. (2020). The Transformation of Di- and Tri-chloromethane Induced By Low Voltage Discharge. KnE Materials Science, 6(1), 401–408. https://doi.org/10.18502/kms.v6i1.8117

https://doi.org/10.18502/kms.v6i1.8117

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authors

  • Bodrikov Ivan Vasilievich

    Bodrikov Ivan Vasilievich

    Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Nizhny Novgorod Region, Russia
  • Grinvald Iosif Isaevich

    Grinvald Iosif Isaevich

    Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Nizhny Novgorod Region, Russia
  • Titov Evgeniy Yuryevich

    Titov Evgeniy Yuryevich

    Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Nizhny Novgorod Region, Russia
  • Titov Dmitry Yuryevich

    Titov Dmitry Yuryevich

    Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Nizhny Novgorod Region, Russia
  • Razov Evgeniy Nikolaevich

    Razov Evgeniy Nikolaevich

    Institute of Mechanical Engineering Problems, Russian Academy of Sciences, Nizhny Novgorod, Nizhny Novgorod Region, Russia

Published Date

  • Dec 31, 2020

The Transformation of Di- and Tri-chloromethane Induced By Low Voltage Discharge

KnE Materials Science / IV Congress “Fundamental Research and Applied Developing of Recycling and Utilization Processes of Technogenic Formations” Volume 2020 / Pages 401–408

Abstract




This article is focused on the transformation of di- and trichloromethane by induced low-voltage discharges in the liquid phase. To generate discharges, a direct current source is used (capacitance 2200 μF, voltage 60 V). The products and probable intermediates of the CH2Cl2 and CHCl3 transformation were determined by the methods of thermodynamic modeling, FTIR spectroscopy and electron microscopy. Under the action of low-voltage discharges on the liquid substrates, needle fullerene- like structures are formed. In this case the gas phase consists mainly of hydrogen chloride. From the simulation of the nonequilibrium composition of particles and molecular systems it follows that in the course of induced reactions of CH2Cl2 and CHCl3 and geminal elimination of HCl molecules, predominantly carbene-type intermediates are generated.





Keywords: dichloromethane, trichloromethane, low temperature plasma, discharges in the liquid phase







References
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