Physico-Chemical Foundation of Sludge Processing Hydrometallurgical Production of Vanadium Pentoxide. Investigation of Forms of Vanadium Compounds

Abstract




To develop the physico-chemical basis of a complex technology for processing slurries hydrometallurgical production of vanadium pentoxide it is necessary to know in what form vanadium compounds are in the dump sludge and at what stage of processing they were formed, which is why vanadium is not completely extracted into the solution. This paper investigates the behavior of vanadium in the existing process chain (with the study of intermediate products of technological conversion) using a set of modern analytical methods (X-ray diffraction, SEM, X-ray diffraction, thermogravimetry).


Keywords: vanadium, slag, sludge, vanadium pentoxide, oxidation state, phase composition, processing technology




References
[1] Liakishev, N. P., et al. (1983). Vanadium in the Steel Industry. Moscow: Metallurgy.

[2] Barolin, H. (1982). Oxidation of Vanadium Slag. Beijing: Metallurgical Industry Press.

[3] Moskalyk, R. R. and Alfantazi A. M. (2003). Processing of Vanadium: A Review. Miner. Eng., vol. 16, issue 9, pp. 793.

[4] Kologrieva, U. A., Seregin, A. N. and Pochtarev, A. N. (2015). Development of Sulphuric Acid Technology for Processing Slimes of Hydrometallurgical Production of Vanadium Pentoxide. Probl. Chern. Metallurg. Materialoved., issue 4, pp. 63-67.

[5] Vygovskaya, I. V. (2002) Development of Physicochemical Principles and Utilization of Technogenic Vanadium-Containing Waste in the Lime-Sulfuric Acid Manufacture Vanadium Pentoxide. (PhD dissertation, Tula state University, 2002).

[6] Kudryavsky, Y. P., et al. (2000). Hydrometallurgical Processing of Vanadium-Containing Waste. Tsvetnaya metallurgiya, issue 1, pp. 25-29.

[7] Junyi, X., et al. (2018). Recovery of Tailings from the Vanadium Extraction Process by Carbothermic Reduction Method: Thermodynamic, Experimental and Hazardous Potential Assessment. Journal of Hazardous Materials, vol. 357, pp. 128–137.

[8] Zhdanov, P. A., et al. (2016). Determination of Forms of Element Occurrence in Samples of Vanadium Slag and Slime. Inorganic Materials, vol. 52, issue 14, pp. 1431–1439.

[9] Rabinovich, E. and Greenberg, E. (2002). Applications of Vanadium. Natsional’naya metallurgiya, issue 2, pp. 33–36.

[10] Zubarev, A. G. and Volkov, V. S. (1986). Development of Low-waste Technology of Ferrovanadium Production. Stal’, issue 2, pp. 50–51.

[11] Kudryavsky, Y. P., et al. (2000). Chlorine Technology for Processing Vanadium-Containing Waste to Produce Commercial Products. Tsvetnaya metallurgiya, issue 8, pp. 24-26.

[12] Kudryavsky,Y.P.,etal.(2000).PyrometallurgicalTechnologyofVanadium-containingWasteProcessing. Tsvetnaya metallurgiya, issue 5-6, pp. 39-40.

[13] Zhdanov, P. A., et al. (2017). Determination of the Mode of Occurrence of V, Fe, and Mn in Slags and Charge of Vanadium Production by X-Ray Spectroscopy. Inorganic Materials, vol. 53, issue 14, pp. 1399–1404.