Download fulltext HTML
D. Linnikov , O., & V. Rodina, I. (2020). Sorption Properties of the Filter Material MS in Relation to Copper(II) Ions. KnE Materials Science, 6(1), 113–119. https://doi.org/10.18502/kms.v6i1.8054

https://doi.org/10.18502/kms.v6i1.8054

statistics

  • 320 Abstract Views
  • 251 PDF Views
  • 0 HTML Views

authors

  • Oleg D. Linnikov

    Oleg D. Linnikov

    Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya St., 620990, Ekaterinburg, Russia
  • Irina V. Rodina

    Irina V. Rodina

    Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya St., 620990, Ekaterinburg, Russia

Published Date

  • Dec 31, 2020

Sorption Properties of the Filter Material MS in Relation to Copper(II) Ions

KnE Materials Science / IV Congress “Fundamental Research and Applied Developing of Recycling and Utilization Processes of Technogenic Formations” Volume 2020 / Pages 113–119

Abstract

The sorption of copper(II) ions by the mineral filter material MS was studied. The study was carried out on a model solution of copper(II) sulfate containing an additional 400 mg/dm3 of sodium sulfate. It demonstrates that the sorption properties of MS are due to the simultaneous action of two factors. The first is associated with an increase in the pH of the solution being purified when the MS material is introduced into it, which leads to the precipitation of copper(II) ions from the solution in the form of the corresponding hydroxide. The second is the ability of the MS to remove copper(II) ions from the solution by the mechanism of adsorption described by the Langmuir equation. It was found that with an increase in the pH of the solution from 4 to 6.7, the adsorption of copper(II) ions on the surface of the MS increases (ranges of pH<4 and pH>6.7 have not been studied). The found values of the MS monolayer capacity with respect to copper(II) ions turned out to be comparable in magnitude with similar values for some other mineral sorbents.


Keywords: copper(II) ions, sorption, Langmuir equation, adsorption capacity

References
[1] Vinogradov, S. S. (2010). The Validity and Invalidity of the Use of the Various Lists of MPC for Stocks of Galvanic Production. Water supply and sewerage, issue 5-6, pp. 113-118.

[2] Markov, V. F., et al. (2007). Extraction of Copper from Industrial Effluents using a Composite Sorbent Strongly Acid Cation Exchange Resin - Hydroxide Glands. International Scientific Journal for Alternative Energy and Ecology, vol. 47, issue 3, pp. 144-149.

[3] Novikov, U. V., Lastochkin, K. O. and Boldina, Z. N. (1990). Methods of research of water quality of reservoirs. Moscow: Meditsina.

[4] Aydin, H., Uzan, S. (2012). Equilibrium and Kinetic Studies of Copper(II) Ion Uptake by Modified Wheat Shells. Desalination and Water Treatment, vol. 44, pp. 296-305.

[5] Coruh, S. (2012). Adsorption of Copper (II) Ions on Montmorillonite and Sepiolite Clays: Equlibrium and Kinetics Studies. Desalination and Water Treatment, vol. 45, pp. 351-360.