Components Influence On Dielectric Properties Of Ferroelectric Composite Materials

Abstract

The dielectric properties of ferroelectric composite (NH4HSO4)x/(PbTiO3)1-x is studied for x ranging from 0,00 to 0,50. Measurements of permittivity were performed by heating-cooling mode temperature range from 130 K to 380 K. The value of the temperature interval of existence of the ferroelectric phase increases by ~5 degrees and independent at the volume fraction of particulate inclusions in composites. It is shown that the inclusion of PbTiO3 particles gives rise to hysteresis upper temperature phase transition, which may indicate a change in the type of phase transition of the second order on the first-order phase transition.

References
[1] K. Uchino, Ferroelectric Devices, CRC Press, Boca Raton, 2nd edition, 2009.


[2] JF. Cordaro, Spacecraft protected by a coating including pyroelectric/ferroelectric particles, and the coating material, in Patent N0.: US 6, 12, 478–259, and the coating material. Patent N0, US 6, 2002.


[3] E. V. Stukova and S. V. Baryshnikov, Stabilization of the Ferroelectric Phase in (KNO3)1–x (BaTiO3)x Composites, Inorganic Materials: Applied Research, 2, no. 5, 434–438, (2011).


[4] E. V. Stukova and S. V. Baryshnikov, Stabilization of the Ferroelectric Phase in (KNO3)1–x (BaTiO3)x Composites, Inorganic Materials: Applied Research, 2, no. 5, 434–438, (2011).


[5] S. V. Baryshnikov, A. Y. Milinskiy, E. V. Charnaya, A. S. Bugaev, and M. I. Samoylovich, Dielectric studies of ferroelectric NH4HSO4 nanoparticles embedded into porous matrices, Ferroelectrics, 493, no. 1, 85– 92, (2016).


[6] R. Pepinsky, K. Vedam, S. Hoshino, and Y. Okaya, Ammonium hydrogen sulfate: A new ferroelectric with low coercive field, Physical Review, 111, no. 6, 1508–1510, (1958).


[7] J. P. Remeika and A. M. Glass, The growth and ferroelectric properties of high resistivity single crystals of lead titanate, Materials Research Bulletin, 5, no. 1, 37–45, (1970).


[8] V. G. Bhide, K. G. Deshmukh, and M. S. Hegde, Ferroelectric properties of PbTiO3, Physica, 28, no. 9, 871–876, (1962).


[9] VL. Ginzburg, Teoriya segnetoelektricheskikh yavlenij [The theory of ferroelectric phenomena], Phys.- Uspekhi, 38, no. 4, 490–525, (1949).