Promising Measures to Reduce the Harmful Effects of Man-made Waste from Ferroalloy Production

Abstract

This article formulates a list of promising measures to reduce the harmful impact of man-made waste from ferroalloy enterprises on the environment: (1) technical measures: replacement of the main and auxiliary obsolete equipment with new environmentally safe, allowing to significantly reduce or completely eliminate hazardous emissions and the formation of unclaimed production waste; (2) introduction of energy-saving technologies: the use of physical and chemical energy of top gas from ore-reduction furnaces in turbine generators and in the contrivance for preheating and partial reduction of charge materials elements, etc.; (3) prevention and localization of emissions due to the modernization of existing equipment: sealing and shelter of the main melting equipment, places of loading and unloading of bulk materials, prevention of dusting for the ore materials warehouses, tailing ponds, sludge collectors, etc.; (4) cleaning of harmful emissions, the formation of which cannot be prevented; (5) introduction of innovative waste-free and low-waste technologies with the integrated use of raw materials: utilization of accumulated and current waste (slags, sludge, etc.) that form during the production of ferroalloys, reducing or completely eliminating the waste dumps and sludge collectors; (5) deeper ore preparation with the exception of the use of toxic reagents; and (6) more complete and economical use of water, the creation of closed water systems, the use of modern highly efficient treatment facilities, etc.


Keywords: metallurgy, ferroalloys, man–made wastes, slag, sludge

References
[1] Lisin V.S., Yusfin Yu.S. (1998). Resource and environmental problems of the XXI century and metallurgy. Moscow: High School


[2] Zhuchkov V.I., Zayakin O.V. (2010). Environmentally protective measures in ferroalloy production. Rasplavy, no 4, pp. 66–69.


[3] Zhdanov A.V., Zhuchkov V.I., Dashevskiy V.Ya., et al. (2014). The use of ferroalloy production waste. Stal’, no. 3, pp. 92–98.


[4] Beukes J. P., Dawson N. F., Van Zyl P.G. (2010). Theoretical and practical aspects of Cr (VI) in the South African ferrochrome industry. Proceedings of the Twelfth International Ferroalloys Congress. Sustainable Future. Helsinki, Finland.


[5] Privalov О., Abdulabekov Ye., Nurmukhanbetov Zh., et.al. (2013). Adjustment of idgh carbon ferrochrome composition in DC furnaces. Proceedings of Thirteenth International ferroalloys congress. Almaty, Kazakhstan: Infacon – XIII.


[6] Lyakishev N.P., Gasik M.I. (1999) Chromium metallurgy. Moscow: ELIZ.


[7] Yaroshenko Yu.G., Gordon Ya.M., Hodorovskaya I.Yu. (2012). Energy effective and resource -saving technologies of ferrous metallurgy. Yekaterinburg: UIPC.


[8] Kastcheev I.D., Zemlyanoy K.G., Dosekenov M.S. et al. (2012). The main characteristics of slags and dust formed during the production of ferrochrome. Proceedings of the int. congress ”Fundamental basis of technologies for processing and recycling of man-made waste”. Ekaterinburg: “UIPC”


[9] Matsumoto, T., Tobo H., Watanabe K. (2017). Ironmaking and steelmaking slag products and its new effective utilization technology JFE Giho, no. 40, p. 1–6.


[10] Perepelicin V.A., Rytvin V.M., Gilvarg S.I. et al. (2014). Aluminothermic ferroalloys slags. Ekaterinburg: Uralskiy rabochiy.


[11] Velichko B.F., Gasik M.I., Koval A. V. (1991). Complex technology for the disposal of waste slags, dusts and sludges formed during the smelting of manganese alloys and electrofused. Steel, no. 10, pp. 74–78.


[12] Yaroshenko Yu.G., Gordon Ya.M., Hodorovskaya I.Yu. (2012). Energy effective and resource saving ferrous metallurgy technologies. Ekaterinburg: UIPC.


[13] Ochiai T., Inoue Y., Tanimoto F. et al. (2017). Application of ”Ferroform” to concrete pavement. JFE Giho, no. 40, pp. 51–56.


[14] Midander K., Frutos A. De, Hedberg Y. et al. (2010). Bioaccessibility of ferro– chromium and ferro–silicon–chromium particles compared to pure metals and stainless steel – aspects of human exposure. Proceedings of the Twelfth International Ferroalloys Congress. Sustainable Future. Helsinki, Finland.


[15] Stockmann–Juvala H., Zitting A., Wailinder I., et al. (2010). Use of read–across in the health risk assessment of ferrochromium alloys under REACH. Proceedings of the Twelfth International Ferroalloys Congress. Sustainable Future. Helsinki, Finland.


[16] Kascheev I.D., Dosekenov M.S., Zemlyanoy K.G., et. al. (2012). Recycling of technogenic wastes from the production of high–carbon ferrochrome for refractory materials. Journal of International Scientific Publications «Materials, Methods & Technologies», vol. 6, part 3, pp. 154–164.


[17] Dosekenow M.S., Zhuchkov V.I., Izbembetov D.D., et al. (2012). Formation and use of the man-made wastes in ferroalloys production. Proceedings of the int. congress ”Fundamental basis of technologies for processing and recycling of man-made waste”. Ekaterinburg: LLC “UIPC”.


[18] Fadeev V.I., Ostrovskiy Ya.I., Veselovskiy I.A. et al. (2009). Processing of chromic slags in the conditions of OJSC ”SZF. Proceedings of the All-Russian Conf. with elements of a school for young scientists. Ekaterinburg: Ural Center for Academic Services.


[19] Guloyan Yu.A., Smirnov V.F., Katkova K.S. et al. (1973). Improving the efficiency of the production of painted bottles using ferrochromium slags. Abstracts. meeting ”Improving the efficiency of technological processes in the production of glassware.”. Moscow.


[20] Vasilieva S.N., Menajieva R.A., Shirokov A.F. (1973). The effectiveness of liming for the acidic soils of the Tyumen region by metallurgical slags. Slags of ferrous metallurgy. Proceedings UralNIIChM.


[21] Akberdin A.A., Kim A.S., Ilmaz O.Y. et al. (2013). Boron in ferroalloy production, in Proceeding of the XIII INFACON. Almaty.


[22] Sheshukov O.Yu, Mikheenkov M.A., Nekrasov I.V. (2017). Utilization issues of refining slags for steelmaking: monograph, Nizhniy Tagil: NTI UrFU.


[23] Ghose A., Chopra S., Young J.F. (1983). Microstructural characterization of doped dicalcium silicate polymorphs. J. Mater. Sci, vol. 18, pp. 2905–2914.


[24] Akberdin A.A., Zhuchkov V.I., Kim A.S. (2017). Stabilization of decayed metallurgical slugs. Proceedings of the congress with int. participation and conf. of young scientists ”Fundamental research and applied development of the processes of processing and utilization of technogenic formations”. Ekaterinburg: UB RAS.


[25] Grabeliks A.A., Demin B.L., Kairakbaev S.N. (2010). New technologies of crystalchemical stabilization of slag production for refined ferrochrome. Stal’, no 5, pp. 78– 83.