In this article, the possibility of application of simultaneous homogeneous and heterogeneous doping has been described for the first time. The composite 0.7Ba1.95In2O4.9F0.1⋅0.3Ba2 InNbO6 has been obtained by in situ solid-state method. The scanning electron microscopy and thermogravimetry investigations have been
carried out; the electrical properties have been examined. It has been proved that simultaneous homogeneous and heterogeneous doping is a prospective method for obtaining high-conductive proton electrolytes.
Keywords: brownmillerite, composite, anionic doping, fluorine