The Effect of Simultaneous Homo- and Heterogeneous Doping on Transport Properties of Ba2In2O5

Abstract

In this article, the possibility of application of simultaneous homogeneous and heterogeneous doping has been described for the first time. The composite 0.7Ba1.95In2O4.9F0.1⋅0.3Ba2 InNbO6 has been obtained by in situ solid-state method. The scanning electron microscopy and thermogravimetry investigations have been
carried out; the electrical properties have been examined. It has been proved that simultaneous homogeneous and heterogeneous doping is a prospective method for obtaining high-conductive proton electrolytes.


Keywords: brownmillerite, composite, anionic doping, fluorine

References
[1] Yao, T., Uchimoto, Y., Kinuhata, M., et al. (2000). Crystal structure of Ga-doped Ba2In2O5 and its oxide ion conductivity. Solid State Ionics, vol. 132, pp. 189–198.


[2] Kakinuma, K., Yamamura, H., Haneda, H., et al. (2001). Oxide-ion conductivity of (Ba1−