Download fulltext HTML
Potanina, E. A., Mikhailov, D. A., Boldin, M. S., Nokhrin, A. V., Sakharov, N. V., Belkin, O. A., Lantsev, E. A., & Tokarev, M. G. (2018). Tungstate Based Ceramics Obtained By Spark Plasma Sintering Method – Possible Material for Consolidation of Radioactive Wastes’ Components. KnE Materials Science, 4(1), 566–574. https://doi.org/10.18502/kms.v4i1.2211

https://doi.org/10.18502/kms.v4i1.2211

statistics

  • 264 Abstract Views
  • 186 PDF Views
  • 0 HTML Views

authors

  • E A Potanina
    No author data available.
  • D A Mikhailov
    No author data available.
  • M S Boldin
    No author data available.
  • A V Nokhrin
    No author data available.
  • N V Sakharov
    No author data available.
  • O A Belkin
    No author data available.
  • E A Lantsev
    No author data available.
  • M G Tokarev
    No author data available.

Published Date

  • May 6, 2018

Tungstate Based Ceramics Obtained By Spark Plasma Sintering Method – Possible Material for Consolidation of Radioactive Wastes’ Components

KnE Materials Science / 15th International School-Conference "New Materials – Materials of Innovative Energy" (MIE) / Pages 566–574

Abstract

The Spark Plasma Sintering method was used to produce high-density ceramics from tungstates SrWO4 and NaNd(WO4)2 with scheelite structure. These compounds are proposed as possible matrices for the consolidation of radwaste components. Powder samples were obtained by coprecipitation method and studied by X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). After sintering, the samples retained their phase identity (scheelite structure). The total duration of sintering was ∼ 13-15 min, the relative density was reached ∼ 92, 99%.


Keywords: Tungstates, RW, Spark Plasma Sintering, high density, microstructure

References
[1] G.J. McCarthy, M.T. Davidson, Bull. Am. Ceram. Soc. 54 (1975) 782.


[2] Lutze, R.WC. Ewing, North-Holland Publishers, Amsterdam (1988) 778.


[3] B.E. Burakov, M.I. Ojovan, W.E. Lee, Imperial College Press, Materials for Engineering, (2010) 1.


[4] C.M. Jantzen, W.E. Lee, M.I. Ojovan, In Book ”Radioactive Waste Management and Contaminated Site Clean-Up. Processes, Technologies and International Experience”. Ed. by: W.E. Lee, M.I. Ojovan, C.M. Jantzen, Oxford, Cambridge, Philadelphia, New Delhi. Woodhead Published Limited, 852 p., Chapter 6, 2013, p. 171.


[5] N. Clavier, R. Podor, N. Dacheux, Journal of European Ceramic Society 31 (6) (2011) 941.


[6] N. Dacheux, N. Clavier, R. Podor, Am. Mineral 98 (2013) 833.


[7] E. Potanina, L. Golovkina, A. Orlova, A. Nokhrin, M. Boldin, N. Sakharov, J. Nuclear Materials 473 (2016) 93.


[8] H.T. Hawkins, D.R. Spearing, D.K. Veirs, J.A. Danis, D.M. Smith, C.D. Tait, W.H. Runde, Chemistry of Materials 11 (1999) 2851.


[9] A.I. Orlova, Radiochemistry 44 (5) (2002) 423.


[10] Yu.F. Volkov, S.V. Tomlin, A.I. Orlova, A.A. Lizin, V.I. Spirjakov, A.N. Lukinikh, Radiochemistry 46 (4) (2003) 319.


[11] A.I. Orlova, In Book: Structural Chemistry of Inorganic Actinide Compounds. Chapter 8. By ed. S.V. Krivovichev, P.C. Burns, I.G. Tananaev. ELSEVIER. Amsterdam, (2007) 315.


[12] D.J. Gregg, I. Karatchevtseva, G.J. Thorogood, J. Davis, B. Bell, M. Jackson, P. Dayal, M. Ionescu, G. Triani, K. Short, G.R. Lumpkin, E.R. Vance, J. Nucl. Mater. 446 (2014) 224.


[13] A.I. Orlova, A.K. Koryttseva, E.E. Loginova, Radiochemistry, 53 (1) (2011) 51.


[14] A.I. Orlova, N. Malanina, V.N. Chuvildeev, M.S. Boldin, N.V. Sakharov, A.V. Nokhrin, Radiochemistry 56 (4) (2014) 322.


[15] D. Errandonea, F.J. Manjón, Prog. Mater. Sci. 53 (2008) 711.


[16] B. Macey, Thesis. Master of geological science. Blacksburg: Virginia Polytechnic Institute and State University (1995) 69 p.


[17] A.M. Golub, V.N. Maxin, Sov. J. Inorg. Chem. 22 (1) (1977) 115.


[18] A. Tabuteau, M. Pages, W. Freundlich, Mat. Res. Bull 7 (7) (1972) 631.


[19] M.R. Lee, P. Mahe, C. r. Acad. Sci. Paris 279 (26) (1974) 1137.


[20] M.R. Lee, P. Mahe, C. r. Acad. Sci. Paris 282 (3) (1976) 161.


[21] A.I. Kryukova, G.N. Kazantsev, R.A. Bragina, Sov. Radiochemistry 29 (5) (1987) 599.


[22] A. Tabuteau, M. Pages, J. Inorg. Nucl. Chem. 42 (3) (1988) 401.


[23] A.I. Kryukova, I.A. Korshunov, Sov. Trudi po chimii i chimicheskoi technologii 2 (1965) 95.


[24] M.G. Tokarev, E.A. Potanina, A.I. Orlova, M. Yu. Kalenova, Book of Abstracts of VI all-Russian youth school on radiochemistry and nuclear technology, Ozyorsk, 2014, p. 48.


[25] V. K. Trunov, V. A. Efremov, Yu. A. Velikodniy, Crystal chemistry and properties of double molybdates and tungstates - Leningrad: Publishing House ”Nauka”, Leningrad branch, (1986) pp. 173


[26] V. A. Morozov, A. V. Mironov, B. I. Lazoryak, J. Solid State Chem., 179 (4) (2006) 1183.


[27] D. Errandonea, F. J. Manjón, Prog. Mater. Sci. 53 (2008) 711.


[28] H.R. Williams, H. Ning, M.J. Reece et al., J. Nucl. Mat. 433 (1-3) (2013) 116.


[29] R. C. O’Brien, R.M. Ambrosi, N. P. Bannister, S. D. Howe, H. V. Atkinson, J. Nucl. Mat. 393 (2009) 108.


[30] A. I. Orlova, A. K. Koryttseva, A. E. Kanunov et al., Inorg. Mat. 48 (3) (2012) 98.


[31] A.I. Orlova, A.N. Troshin, D.A. Mikhailov et al., Radiochemistry 56 (1) (2014) 87.