Design Process of Hydrolysis and Fermentation Bioethanol Production from Seaweed Eucheuma cottonii to Renewable Energy Sovereignity
Abstract
The aim of this research was study of E. cottonii to produce bioethanol fermentation substrate with a high reduction sugar content and low Hidroxymethilfurfural (HMF). Fermentation done by instant yeast and Saccharomyces cerevisiae culture of FNCC 3012.The best treatment was obtained in the combination of 2% of H2SO4 by time reaction of 120 minutes in 80°C produced 15.61 g/l reducing sugar and 5.03 g/l HMF. In fermented process, the hydrolysate with instant yeast starter delivered much more efficiency in 3.63 ml CO2 volume, 87.53% in fermentation efficiency, and 1.96 g/l reducing sugar on fifth day of fermentation.
Keywords: bioethanol, Eucheuma cottonii, fermentation, hydrolysis, process design
References
Candra, Krishna Purnawan, Sarwono, Sarinah. 2011. Study on Bioethanol Production using Red Seaweed Eucheuma cottonii From Bontang Sea Water. Journal of Coastal Development Volume: 15 Number: 1, October 2011 : 45 – 50.
Clark, T. Dan K. L. Mackie. 1984. Fermentation Inhibition in Word Hydrolisates Derived from the Softwood Pinus radiate. J. Chem. Bioetechnol. Vol. 34B: 101-110.
Fardiaz, S. 1988. Physiology of Fermentation. Resource and Information Institute, IPB Bogor.
Howard, R.L., E. Abotsi, J.E.L., Rensburg, V. and Howard, S. 2003. Lignocellulose Biotechnology: Issues of Bioconversion and Enzyme Production. African Journal of Biotechnology. 2(12):602 − 619.
Iranmahboob, J., Nadim, F., dan Monemi, S., 2002. Optimizing acid-hydrlysis: a critical step for production of ethanol from mixed wood chips. Biomass and Bioenergy, 22: 401 – 404.
Irawan, D. dan Zainal, A. 2012. Hydrolysis Processing of Organic Waste Being Sugar with Hydrochloric Acid Catalysts. In the Journal of Chemical Engineering: Volume 6, No 2 no page 3640.
Isroi. 2014. Bioethanol Production Calculation in http://isroi.com/ 2010/06/14/bioethanol-production calculation/ Accessed on 15 May 2014.
Marine and Fisheries Ministry. 2011. 2012, KKP Seaweed Production Targets 5.1 Million Tons. In www.kkp.go.id.
Mangunwidjaja, D dan Suryani.A. 1994. Technology Bioproses. Penebar Swadaya, Jakarta.
Meinita MD, Yong-Ki, H., and Gwi-Taek, J. 2011. Comparison of Sulfuric and Hidrochloric acids as Catalyst in Hydrolysis of Kappaphycus alvarezzii (cottonii). Bioprocess Biosyst Eng. (2012) 35:123-128
Nurdin, I.N. 2012. Evaluation of the Quality and Post Harvest Handling Seaweed Eucheuma cottonii Buto n in Southeast Sulawesi Province. Thesis Graduate Program Faculty of Agricultural Technology Universitas Gadjah Mada.
Palmqvist, E., and Hahn-Hägerdal, B., 2000. Review paper. Fermentation of lignocellulosic hydrolysates. II: inhibitors and mechanisms of inhibition. Bioresource Technology, 74, 25-33.
Park, J.-H., Hong, J.-Y., Jang, H. C., Oh, S. G., Kim, S.-H., Yoon, J.-J., and Kim, Y. J. 2011. Use of Gelidium amansii as a promising resource for bioethanol: A practical approach for continuous diluteacid hydrolysis and fermentation. Bioresource Technology, 108, 83–88.
Prescot, S. C. dan C. G. Dunn. 1981. Industrial Microbiology. McGraw-Hill Book Co. Ltd. New York
Puspawati, S., Wagiman, Makhmudun, A., Darmawan, A. N., dan Haslianti. 2015. The Production of Bioethanol Fermentation Substrate from Eucheuma cottonii Seaweed through Hydrolysis by Cellulose Enzyme. Agriculture and Agricultural Science Procedia 2015, Vol. 3 200-205.
Samsuri, M. 2007. Utilization of Cellulosic Ethanol Production Through Baga for Saccharificati on and Fermentation Simultaneously with Xylanase enzyme. Jakarta: Makara Technology.
Tan, I., Man K., and Keat, T. 2013. Hydrolysis of macroalgae using heterogeneous catalyst for bioethanol production. Carbohydrate Polimers Science Direct 94 (2013) 561-566
Wiratmaja, I.G., I.G.B. Wijaya, K., dan I. N. Suprapta, W. 2011. Making the Second Generation of Ethanol by Utilizing Waste of Eucheuma Cottonii as Raw Materials. Scientific Journal of Mechanical Engineering.Vol. 5 No.1: 75-84.