KnE Engineering | XIX International scientific-technical conference “The Ural school-seminar of metal scientists-young researchers” | pages: 41–46

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1. Introduction

The development of technology imposes requirements for increased strength and efficiency to steels in various fields of application. During the last 20-30 years, considerable attention in our country and abroad has been paid to the problem of ionic modification of the surfaces of structural materials. Compared with traditional methods of chemical-heat treatment, ion implantation allows to reduce the time by tens of times and dramatically reduce the processing temperature, as well as improve the protective and strength properties of products [1-3].

The aim of this work is to study the possible mechanisms of structure formation, phase composition, physical-mechanical and service properties of austenitic steels of different composition after bombardment with nitrogen ions N +.

2. Research Methodology

Four grades of corrosion-resistant steels (02H16N10M2, 08H15AG10D2, 06H15AG9NM2 and 09H15AG9ND2) were investigated. The samples for the study were cut from a thin (1 mm) sheet obtained by cold rolling, followed by annealing at 680 C and implantation with N + ions with different radiation doses (0.01 % - irradiation regime 1, 0.1 % - irradiation regime 2). After irradiation, the samples were subjected to recrystallization annealing at a temperature of 300 C for 1 hour. The chemical composition of steel is given in table 1.

Table 1

The chemical composition of the investigated steels.


Steel grade (№ sample) Class C Si Mn S P Cr Ni Mo Cu N
02H16N10M2 (2) Austenite 0.018 0.51 1.38 0.001 0.023 16.12 10.17 2.04    - 0.037
08H15AG10D2 (5) Austenite 0.08 0.32 9.78 0.002 0.030 14.5 0.16    - 1.62 0.163
06H15AG9NM2 (6) Austenite 0.06 0.32 9.20 0.003 0.025 14.8 0.95 1.68    - 0.166
09H15AG9ND2 (15) Austenite 0.094 0.34 8.98 0.005 0.060 15.35 1.16 0.10 1.66 0.1330

To solve this goal, an ion implantation unit was used to double-irradiate samples with a gas ion beam with an energy of up to 40 keV. Mechanical testing of samples for uniaxial tension was performed according to GOST 11701-84 using a TiniusOlsenH50KS machine. The microstructure of the steel was investigated on a metallographic inverted digital complex Axio Zoom V16 manufactured by Carl Zeiss using an image analysis program SIAMS 700. The hardness was determined on a Vickers instrument with a load of 0.049 kN. X-ray structural method was used to determine the phase composition of steels and lattice parameters. The survey was performed on an XRD-7000 X-ray diffractometer.

3. Research Results

The microstructure of the investigated steels is a fine-grained twinned austenite. According to the results of X-ray structural studies, the structure of the steel in the initial state (after cold rolling and quenching from 1050 C in water) consisted only of austenite, within the accuracy of the method.

The mechanical properties of the steels are given in Table 2. Steel 02H16N10M2 has the lowest strength and ductility, in which the nitrogen content is significantly lower than in other steels. The highest properties showed 08H15AG10D2 and 09H15AG9ND2 steels, which, in addition to nitrogen, contain copper.

Table 2

Mechanical properties of steel.


№ sample Steel grade Irradiation regime σyield , [MPa] σuts , [MPa] δ , % ψ , %
2 02H16N10M2    - 220 580 31 40
1 280 650 21 30
2 280 640 37 42
5 08H15AG10D2    - 520 1050 39 40
1 450 840 22 23
2 470 1130 46 25
6 06H15AG9NM2    - 370 870 43 42
1 330 730 27 27
2 360 930 49 41
15 09H15AG9ND2    - 510 970 37 40
1 490 880 23 24
2 460 980 48 41

The microstructure of all the investigated steels after irradiation regime 1 and recrystallization revealed some grinding of austenite grain. The structure of steels 02H16N10M2 and 08H15AG10D2 changed little under the action of irradiation (Figures 1, 2; a, b), as did the austenitic structure with ultrafine grains (2-4 μm) in 09H15AG9ND2 steel (Figure 1, 2; d). In steel 06H15AG9NM2, austenite was observed with annealing twins, but with a larger grain.

Further grinding of austenite grain after the bombardment with nitrogen ions in regime 2 was not observed (Figure 2). In all samples, after irradiation, an increase in strength was observed without a significant change in plasticity, as well as in hardness, which is associated with an increase in the density of defects and the appearance of deformation martensite (Figure 3).

fig-1.jpg
Figure 1
The microstructure of the steel after irradiation regime 1: a – steel № 2; b – steel № 5; c – steel № 6; d – steel № 15.
fig-2.jpg
Figure 2
The microstructure of the steel after irradiation regime 2: a – steel № 2; b – steel № 5; c – steel № 6; d – steel № 15.
fig-3.jpg
Figure 3
Steel hardness before and after irradiation: a – steel № 2; b – steel № 5; c – steel № 6; d – steel № 15.

4. Conclusions

  • In the studied steels after ion implantation, an increase in the mechanical characteristics of the alloy is observed: hardness HV on average by 1.5-2 times, σuts – by 50-60 %. The increase in HV and σuts is due to an increase in the concentration of defects in the alloy structure.

  • The yield strength ( σyield ) of the investigated steels during the implantation of N + ions increases on average by 10-20 %. Its increase depends on the method of implantation and the degree of deformational aging of steels, in particular, as a result of copper extraction, as in samples 5 and 15.

  • The grain size of austenite after implantation, accompanied by heating to 70-250 C, in all steels decreases due to the fragmentation of the grains with increasing dislocation density.

  • Irradiation with nitrogen ions of austenitic corrosion-resistant steels can be considered effective for enhancing the mechanical properties during operation in air and in a corrosive environment.

References

1 

Kalin B. A. Radiatsionno-puchkovyye tekhnologii obrabotki konstruktsionnykh materialov / B. A. Kalin // Fizika i khimiya obrabotki materialov. 2001, № 4. P. 5-16.

2 

Goncharov V. V. Mikrotverdost' poverkhnosti nerzhaveyushchey stali, modifitsirovannoy ionnoy implantatsii // Problemy mashinostroyeniya, 2013, T. 16, № 6. P. 47-51.

3 

Budzinski P., Polyanski K., Kobzev A.P. Izmeneniye svoystv poverkhnosti nerzhaveyushchey marki AISI316L, implantirovannoy azotom // Poverkhnost'. Rentgenovskiye, sinkhrotronnyye i neytronnyye issledovaniya. 2008, № 8. P. 80-85.

4 

Povysheniye iznosostoykosti stali 30KHGSN2A implantatsii ionov azota i ionov metalla / A. A. Yarnykh [i dr.] // Materialovedeniye. 2014. № 11. P. 30-34.

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